The objective of this chapter is to highlight the logistics system in the Agri-food chain and present case studies. In most of the case studies, mapping out the material flow; investigating the possibilities and constraints of coordinated and integrated collection of primary production and goods distribution; and investigating the food products and means of production that supported by information technology were carried out. Optimization of collection/distribution and the reduction in emissions from the vehicles as a result of optimization are presented. It is assumed that the information achieved through this investigation will assist to develop an effective transport-logistics system, which may enable an efficient utilization of vehicles to meet the current demand for attenuating environmental impacts.